Product Name: Propyl Acetate
Synonyms: n-Propyl acetate, 1-Propyl acetate
Chemical Formula: C5H10O2
CAS Number: 109-60-4
Recommended Use: Solvent for inks, coatings, resins, fragrances
Supplier Details: Refer to local distributor or manufacturer
Emergency Phone: Refer to regional or manufacturer-specific contact
GHS Classification: Flammable liquids (Category 2), Eye irritation (Category 2A), Specific target organ toxicity - single exposure (Category 3)
Label Elements: Flame, Exclamation mark pictograms
Signal Word: Danger
Hazard Statements: Highly flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness.
Precautionary Statements: Avoid breathing vapor or mist. Keep away from heat/sparks/open flames/hot surfaces. Use explosion-proof electrical equipment.
Other Hazards: Vapors may form explosive mixtures with air. May cause irritation to skin and respiratory system.
Chemical Name: Propyl Acetate
Concentration: >99%
CAS Number: 109-60-4
Impurities: Trace levels (usually below reporting threshold), specific composition can vary with supplier
Inhalation: Move person to fresh air immediately. Get medical attention if symptoms persist like coughing or dizziness.
Skin Contact: Remove contaminated clothing. Wash affected skin with plenty of water and mild soap.
Eye Contact: Rinse eyes thoroughly with clean water for at least 15 minutes. Lift eyelids to ensure rinsing. Seek medical attention promptly.
Ingestion: Do not induce vomiting. Rinse mouth. Get medical help if feeling unwell. Do not give anything by mouth to an unconscious person.
Important Symptoms: Headache, dizziness, irritation of eyes and respiratory tract. Prolonged or repeated skin contact can result in dryness or cracking.
Suitable Extinguishing Media: Alcohol-resistant foam, dry chemical powder, carbon dioxide.
Unsuitable Media: Direct water jets (may spread fire).
Special Hazards: Highly flammable liquid and vapor. Vapors may travel and ignite at distance. Hazardous combustion products may include carbon monoxide and carbon dioxide.
Protective Equipment for Firefighters: Full protective gear and self-contained breathing apparatus.
Additional Advice: Cool storage tanks and containers with water spray. Evacuate area. Prevent runoff from entering drains.
Personal Precautions: Evacuate non-essential personnel. Eliminate all ignition sources. Use proper personal protective equipment (PPE).
Environmental Precautions: Prevent further leakage or spillage if safe. Stop entry into drains, sewers, or waterways.
Clean-Up Methods: Contain spill with inert absorbent material such as sand or earth. Collect in suitable, closed containers for disposal. Provide adequate ventilation. Wash spill area after material pickup is complete.
Precautions for Safe Handling: Keep container tightly closed. Avoid contact with eyes, skin, and clothing. Avoid breathing vapors. Use only in well-ventilated areas. Ground and bond containers when transferring.
Conditions for Safe Storage: Store in a cool, dry, well-ventilated area. Keep away from heat, open flames, and strong oxidizers. Keep container tightly closed when not in use.
Special Storage Needs: Use proper grounding procedures. Keep out of reach of children. Protect from sunlight and incompatible materials.
Occupational Exposure Limits: ACGIH TLV: 200 ppm TWA, 250 ppm STEL (short term exposure limit).
Engineering Controls: Use explosion-proof local exhaust ventilation to minimize exposure.
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), safety goggles or face shield for eye protection, flame-retardant antistatic clothing, suitable respiratory protection if ventilation is inadequate.
General Hygiene: Do not eat, drink, or smoke while handling. Wash hands thoroughly after use.
Appearance: Colorless liquid
Odor: Fruity, characteristic odor
Odor Threshold: 0.2 ppm
pH: Not applicable
Melting Point: -95°C
Boiling Point: 101°C
Flash Point: 16°C (closed cup)
Evaporation Rate: 0.5 (butyl acetate = 1)
Flammability: Highly flammable
Explosion Limits: Lower 1.7%, Upper 8.0% (volume in air)
Vapor Pressure: 24 mmHg @ 20°C
Vapor Density: 3.5 (air = 1)
Relative Density: 0.888 (water = 1)
Solubility: 1.7 g/L water @ 20°C; soluble in ethanol, ether
Partition Coefficient (log Kow): 1.2
Auto-ignition Temperature: 460°C
Decomposition Temperature: Undetermined
Viscosity: 0.7 mPa·s @ 20°C
Chemical Stability: Stable under normal temperatures and pressure.
Hazardous Reactions: Can react with strong oxidizing agents, strong acids or bases.
Conditions to Avoid: Heat, flames, sparks, static discharge, and all ignition sources.
Incompatible Materials: Strong oxidizing agents, strong acids, alkalis.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, other unidentified organic compounds under fire conditions.
Acute Toxicity - Oral (LD50): 8700 mg/kg (rat)
Acute Toxicity - Inhalation (LC50): > 21 mg/L (rat, 4h)
Acute Toxicity - Dermal (LD50): > 17700 mg/kg (rabbit)
Skin Corrosion/Irritation: May cause mild skin irritation
Eye Damage/Irritation: Causes serious eye irritation
Respiratory Sensitization: May cause respiratory irritation, drowsiness or dizziness
Chronic Effects: Prolonged exposure may cause skin dryness or cracking
Carcinogenicity: Not classified as carcinogen by IARC, NTP, OSHA
Other Data: No evidence of reproductive or developmental toxicity in available animal studies
Ecotoxicity - Fish (LC50): 100 mg/L (96 h, Lepomis macrochirus)
Ecotoxicity - Daphnia (EC50): 260 mg/L (48 h, Daphnia magna)
Ecotoxicity - Algae (EC50): 94 mg/L (72 h, Pseudokirchneriella subcapitata)
Persistence and Degradability: Readily biodegradable (90% in 28 days)
Bioaccumulation: Log Kow 1.2 suggests low potential
Mobility in Soil: Moderately mobile, may leach to groundwater
Other Adverse Effects: Not regarded as persistent, bioaccumulative, or toxic; avoid release to the environment
Waste Disposal Methods: Send waste and residues to authorized hazardous waste disposal contractor. Follow all local, state, and federal regulations.
Container Disposal: Empty containers may contain hazardous residues. Do not reuse containers. Puncture and dispose safely.
Special Cautions: Do not discharge to surface waters, sewers, or soil. Always wear appropriate protective equipment when handling waste.
UN Number: 1276
Proper Shipping Name: Propyl Acetate
Transport Hazard Class: 3 (Flammable Liquid)
Packing Group: II
Labels: Flammable liquid (pictogram, class 3)
Marine Pollutant: No
Environmental Hazards: No significant risk under normal transport
Transport Precautions: Keep package upright and away from ignition sources, avoid rough handling, secure in transport
Regulatory Transport Codes: ADR/RID: 3, IMDG: 3, IATA: 3
EU Regulation: REACH registered, included in Annex VI of Regulation (EC) No 1272/2008 (CLP)
OSHA Status: Recognized as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
SARA Title III Sections 311/312: Fire, acute health hazard
TSCA Inventory: Listed
DSL/NDSL (Canada): Listed on DSL
Proposition 65 (California): Not listed
Other Regulations: Complies with key international chemical safety and transport regulations
